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IRC

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Client Software @
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Websites
Nearly 800 helpful files including FAQs, primers, technical guides, clients and scripts, and server lists and maps.
http://www.irchelp.org/

Contains links, explanations, guides, and many good documentations.
http://www.hut.fi/~jlohikos/IRC.html

Resources for Undernet server operators.
http://routing-com.undernet.org/

UnderNet's IRC-related FAQ
http://www.faqs.org/faqs/irc/undernet-faq/part1/index.html

Specifications for CTCP as well as DCC protocols which are now standard supplements of IRC.
http://www.irchelp.org/irchelp/rfc/ctcpspec.html

Advanced reference of IRC commands.
http://www.student.uib.no/~st01369/ccosmos/

Based on the chatting client, this is a good explanation on how to get started, easily. Contains plenty of other related links.
http://www.mirc.com/irc.html

IRC Protocol
http://www.irchelp.org/irchelp/rfc/